Skip to main content

Full text of "Treatise On Applied Analytical Chemistry(Vol-1)"

See other formats



or if very exact results are required, the picnometer. The determination
should be made at 15 or referred to 15, the mean temperature coefficient
of specific gravity being 0-0007 (0-0006-0-0008) per i.

2. Fractional Distillation.In order that concordant results may
be obtained, this should always be carried out under certain definite con-
ditions and in an apparatus of fixed dimensions. Engler's flask, shown
in Fig. 40, is generally used. 100 c.c. of the oil are placed in the flask
which is connected with a condenser 60 cm. long and heated, both the flame
and the flask being protected with a sheet metal mantle.

The initial temperature of distillation is that at which the first drop
of distillate issues from the condenser fitted to the side-tube of the flask.
The velocity of distillation should be such that two drops pass over per
second. The distillate is collected in several graduated cylinders, or in a
single 100 c.c. cylinder in which the volumes of the distillates at the different

FIG. 40

FIG. 41

temperatures are read off successively. The distillation is at an end when
the flask contains only residuum or white fumes appear. The fractions
usually collected are :

Benzine:   up to 150 C.

Lamp oil:   150-300.

Heavy oils :   above 300.

In the Italian Customs Laboratory, for the determination of the frac-
tions distilling below 310 for fiscal purposes, use is made of a flask similar
to the preceding but of the dimensions shown in Fig. 41. 100 c.c.
of the petroleum are then distilled, the flask being heated over a gauze
by a small flame ; subsequently the flame is enlarged, and it may finally be
necessary to surround the flask with an asbestos mantle. The rate of dis- physical and partly chemical.